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题名: Studies on the spin Hamiltonian parameters of vitamin B(12r)
作者: S. Y. Wu;  L. H. Wei;  Z. H. Zhang;  X. F. Wang
发表日期: 2009
摘要: The spin Hamiltonian parameters g factors g(i) (i = x,y,z) and the hyperfine structure constants A(i) of vitamin B(12r) have been theoretically studied from the perturbation formulas of these parameters for a Co(2+) (3d(7)) ion with low spin (S = 1/2) in rhombically distorted octahedra. The related crystal-field parameters are determined from the point-charged dipole model and the local structure around Co(2+) in vitamin B(12r). The theoretical spin Hamiltonian parameters are in good agreement with the experimental data. (C) 2008 Elsevier B.V. All rights reserved.
KOS主题词: Electron paramagnetic resonance;  Electron paramagnetic resonance spectroscopy;  Electron nuclear double resonance;  crystal;  Infrared spectra;  Spectrum analysis;  Ions;  SYSTEMS;  Field
刊名: Spectrochimica Acta Part a-Molecular and Biomolecular Spectroscopy
相关网址: <Go to ISI>://WOS:000261900000066
Appears in Collections:中国科学院金属研究所_期刊论文

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Recommended Citation:
S. Y. Wu,L. H. Wei,Z. H. Zhang,et al. Studies On The Spin Hamiltonian Parameters Of Vitamin B(12r)[J]. Spectrochimica Acta Part A-molecular And Biomolecular Spectroscopy,2009,71(5):2023-2025.

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